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Cascade alkyl migration in 2-alkynylanilines for the synthesis of benzenoid ring multi-functionalized indoles.
- Source :
-
Chemical Communications . 1/14/2024, Vol. 60 Issue 1, p71-74. 4p. - Publication Year :
- 2024
-
Abstract
- Cascade alkyl migration of 2-alkynylanilines via an aromaticity destruction and reconstruction process is reported. The first alkyl migration is triggered by generation of a dearomatized arenium species via oxidation and cyclization, and the second is driven by the force to restore the aromaticity of rearrangement products. The reaction gave rise to a range of multi-functionalized indoles. [ABSTRACT FROM AUTHOR]
- Subjects :
- *INDOLE compounds
*AROMATICITY
*RING formation (Chemistry)
*OXIDATION
*INDOLE
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 174316588
- Full Text :
- https://doi.org/10.1039/d3cc04815b