Construction of defective ZnIn2S4 and immobilized TiO2 heterostructures: Synergistic regulation of ZnIn2S4/TiO2/MS-SiO2 composite photocatalyst performance.

Defect engineering and heterojunction are the two dominant methods to improve the efficiency of semiconductor photocatalysis. Loading can also improve the performance of photocatalysts and solve the problems of photocatalyst agglomeration and difficult recovery in water. In this paper, a ternary ZnIn 2 S 4 /TiO 2 /MS-SiO 2 composite photocatalyst (EG-ZIS/TS) was constructed by sequentially loading nano-TiO 2 and defective state ZnIn 2 S 4 (EG-ZIS) on industrial by-product SiO 2 microspheres (MS-SiO 2). Among them, EG-ZIS was prepared with ethylene glycol as a solvent. Compared with EG-ZIS/T (unloaded MS-SiO 2) and ZIS/TS (non-defected state ZnIn 2 S 4), the degradation performance of methyl orange (MO) solution and the reduction performance of hexavalent chromium under simulated daylight irradiation were substantially improved. As a result, Zn defects enhanced the photocatalytic performance of ZnIn 2 S 4 and the heterojunction between ZnIn 2 S 4 and TiO 2 , and this enhancement was achieved by adjusting the work function of the system and promoting interface electronic transmission. The loading of MS-SiO 2 further produced a synergistic effect of enhancing the heterojunction photocatalytic efficiency by improving the dispersion and immobilization of TiO 2 and EG-ZIS. The effect of ethylene glycol on the curvature and surface Zn defectivity of ZnIn 2 S 4 nanosheets was also investigated in this study. This study provides an innovative approach to improve the oxidation and reduction performance of photocatalysts by combining semiconductor defect, heterojunction, and loading on the carrier surface and finds that the loading of photocatalysts on the SiO 2 carrier surface has an enhancement effect on the performance of the formed heterojunction. This thesis is useful and informative for related research. [Display omitted] • ZnIn 2 S 4 with surface Zn defects was prepared using ethylene glycol as solvent. • Construct a heterojunction between the defect ZnIn 2 S 4 and nano TiO 2. • Load EG-ZnIn 2 S 4 /TiO 2 onto industrial byproduct SiO 2 microspheres. • Defect, heterostructure, and carrier jointly enhance the performance of photocatalysts. • This paper provides a solution for industrial treatment of pollutants in water. [ABSTRACT FROM AUTHOR]