Tuning the CO2 selective adsorption performance in MOFs by incorporating functional groups on the isophthalate skeleton.

By introducing functional groups into the isophthalate ligand to decorate the pore of the MOFs, gas adsorption and separation performance can be tunable. In this paper, two isostructural 2D Co-MOFs, [Co(5-MIA)(bpy)]·H 2 O (1) and [Co(5-EIA)(bpy)]·H 2 O (2) (5-H 2 MIA = 5-methoxyl-isophthalic acid; 5-H 2 EIA = 5-ethyoxyl-isophthalic acid; bpy = 4,4′-bipyridine), with different functionalized pore surfaces and channel sizes were designed and constructed. The structures and performance of the two Co-MOFs were analyzed by SCXRD, PXRD, IR, TGA, and gas sorption (CO 2 , C 2 H 2 , CH 4 , CO, and N 2). Attributed to the methoxyl of isophthalate skeleton, 1a (activated 1) shows enhanced CO 2 uptake over other gases. In spite of decreased pore sizes (3.49 Å) compared with 2a (4.38 Å), the CO 2 uptake of 1a (43.41 cm3 g−1) is larger than that of 2a (22.39 cm3 g−1) at 298 K and 100 kPa. Compound 1 incorporates methoxyl groups into the narrow channel, and exhibits the cooperative effect of CO 2 -preferential due to adsorbent-adsorbate coactions and size sieving. GCMC simulation has been used to explore the adsorption coactions of CO 2 and 1 , and the results confirmed that the methoxyl groups in the channel are the main binding sites of CO 2. At ambient temperature and 100 kPa, the IAST selectivities of CO 2 /C 2 H 2 (1:1), CO 2 /CH 4 (1:1), C 2 H 2 /CH 4 (1:1), CO 2 /CO (1:2) and CO 2 /N 2 (15:85) on 1a were 2.6, 39.3, 13.3, 282 and 1433, respectively. The easy activation and regeneration, excellent thermal and humidity stability, and good reusability, make 1 a hopeful adsorbent for adsorption and separation of CO 2. By introducing functional groups into the isophthalate ligand to decorate the pore of the MOFs, gas adsorption and separation performance can be tunable. Two isostructural 2D Co-MOFs with different functionalized pore surfaces and channel sizes were constructed and show different C 2 H 2 /CH 4 and C 2 H 2 /CO 2 gas separation properties. [Display omitted] • Title compound represent the first example of 3D MOF based on 5-H 2 MIA and bpy. • 1a (activated 1) shows enhanced CO 2 uptake over C 2 H 2 , CH 4 , CO and N 2. • 1a shows an excellent reuse performance. [ABSTRACT FROM AUTHOR]