Back to Search
Start Over
Structural transformation of Cu-coated multi-walled carbon nanotubes subjected to high-energy laser irradiation.
- Source :
-
Optics & Laser Technology . Apr2024, Vol. 171, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- • Cu coating is melted, desquamated, and solidified into near-spherical particles. • Cu coating can protect MWCNTs from structural damage at a laser power of 600 W. • MWCNTs are cut into segments and transformed into near-spherical amorphous particles. • Spheroidization of amorphous carbon is driven by the reduction in surface energy. The Cu coating on carbon nanotubes (CNTs) with low infrared laser absorptivity was applied to provide a protective layer against the structural damage caused by laser irradiation in this paper. The effect of Cu coating on the structural evolution of multi-walled carbon nanotubes (MWCNTs) under a ring-shaped high-energy laser beam was studied. As the laser power increases, the morphology of 35 wt.% Cu-coated MWCNTs (35Cu-CNTs) samples transforms from discrete fine powder particles to caking structure with a roughened surface. A 45 wt.% Cu coating effectively provides structural protection for MWCNTs against laser-induced damage at a laser power of 600 W. During laser irradiation, the Cu coating melts, detaches from the surface of MWCNTs, and subsequently solidifies into a mixture of nearly spherical particles. Without the protection of Cu coating, the MWCNTs bundles are fragmented into nanoscale segments in varying sizes. These segments undergo a transformation into amorphous carbon particles as a result of the rapid heating and cooling process induced by the high-energy laser irradiation. The thermal impact of the high-energy laser beam plays a crucial role in determining the structural transformation of MWCNTs. The coalescence and spheroidization of amorphous carbon particles can be induced by the reduction of surface energy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00303992
- Volume :
- 171
- Database :
- Academic Search Index
- Journal :
- Optics & Laser Technology
- Publication Type :
- Academic Journal
- Accession number :
- 174500800
- Full Text :
- https://doi.org/10.1016/j.optlastec.2023.110420