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SnO2/SnS heterojunction anchoring on CMK-3 mesoporous network improves the reversibility of conversion reaction for lithium/sodium ions storage.
- Source :
-
Nanotechnology . 3/18/2024, Vol. 35 Issue 12, p1-11. 11p. - Publication Year :
- 2024
-
Abstract
- Tin oxide-based (SnO2) materials show high theoretical capacity for lithium and sodium storage benefiting from a double-reaction mechanism of conversion and alloying reactions. However, due to the limitation of the reaction thermodynamics and kinetics, the conversion reaction process of SnO2 usually shows irreversibility, resulting in serious capacity decay and hindering the further application of the SnO2 anode. Herein, SnO2/SnS heterojunction was anchored on the surface and inside of CMK-3 by in situ synthesis method, forming a stable 3D structural material (SnO2/SnS@CMK-3). The electrochemical properties of SnO2/SnS@CMK-3 composite show high capacity and reversible conversion reaction, which was attributed to the synergistic effect of CMK-3 and SnO2/SnS heterojunction. To further investigate the influence of the heterojunction on the reversibility of the conversion reaction, the Gibbs free energy (Δ G) was calculated using density functional theory. The results show that SnO2/SnS heterojunction has a closer to zero Δ G for lithium/sodium ion batteries compared to SnO2, indicating that the heterojunction enhances the reversibility of the conversion reaction in chemical reaction thermodynamics. Our work provides insights into the reversibility of the conversion reaction of SnO2-based materials, which is essential for improving their electrochemical performance. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SODIUM ions
*LITHIUM
*HETEROJUNCTIONS
*GIBBS' free energy
*THERMODYNAMICS
Subjects
Details
- Language :
- English
- ISSN :
- 09574484
- Volume :
- 35
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Nanotechnology
- Publication Type :
- Academic Journal
- Accession number :
- 174638235
- Full Text :
- https://doi.org/10.1088/1361-6528/ad12e7