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Mechanism insight into highly efficient stabilization of Cd contaminated soils by steam flash heating.
- Source :
-
Journal of Cleaner Production . Jan2024, Vol. 434, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Soil cadmium (Cd) contamination is a world-wide challenge and chemical stabilization is the most used remediation strategy. To solve the disadvantages of high stabilizer dosage and cost, we innovated a cost-efficient steam flash heating (SFH) approach to chemically immobilize Cd in contaminated soils, which introduced high-pressure saturated water vapor into soil microstructure, broke their binding with soil particles and accelerated Cd reactions with stabilizers by ultrafast pressure release. Using calcium dihydrogen phosphate, potassium hydrogen phosphate or calcium carbonate as stabilizer, Cd stabilization efficiency was 10.4%, 13.4% and 17.1% higher by SFH than conventional chemical stabilization, and the lowest Cd content in leachate was 0.61 mg/L. Additionally, SFH approach averagely reduced 50.1 ± 7.29% of stabilizer dosage, 34.1% of cost, and 29.9% of CO 2 emission. BCR sequential extraction results suggested that acid extractable Cd was preferentially transformed into residual Cd by SFH. Analysis of X-ray absorption near edge structure (XANES) documented that SFH treatment produced more stable Cd-minerals of Cd 3 (PO 4) 2 , CaCO 3 -Cd, and CdCO 3. Our findings proved the state-of-the-art SFH approach and uncovered its mechanisms to stabilize Cd in contaminated soils, offering a green and cost-efficient remediation alternative for heavy metal contaminated site management. [Display omitted] • Innovative steam flash heating for effective Cd immobilization. • SFH improves the molecular contact and mass transfer to accelerate Cd stabilization. • Higher cost-efficiency and lower energy consumption in steam flash heating. • Steam flash heating changes Cd immobilization mechanism evidenced by XANES. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09596526
- Volume :
- 434
- Database :
- Academic Search Index
- Journal :
- Journal of Cleaner Production
- Publication Type :
- Academic Journal
- Accession number :
- 174666883
- Full Text :
- https://doi.org/10.1016/j.jclepro.2023.140059