Back to Search
Start Over
Investigation of Mechanochromic Luminescence of Pyrene‐based Aggregation‐Induced Emission Luminogens: Correlation between Molecular Packing and Luminescence Behavior.
- Source :
-
Chemistry - An Asian Journal . 1/2/2024, Vol. 19 Issue 1, p1-12. 12p. - Publication Year :
- 2024
-
Abstract
- To better understand the correlation between molecular structure and optical properties such as aggregation‐induced emission (AIE) and mechanochromic luminescence (MCL) emission, two new pyrene‐based derivatives with substitutions at the 4‐ and 5‐positions (1HH) and at the 4‐, 5‐, 9‐, and 10‐positions (2HH) were designed and synthesized. Cyano groups were introduced at the periphery of the synthesized compounds (1HCN, 1OCN, 1BCN, 2HCN, 2OCN, and 2BCN) to investigate the influence of these groups on the emission properties of the pyrene derivatives both in solution and in the solid state. The fluorescence emission performance of these compounds in water/acetone mixtures was simultaneously studied, revealing outstanding aggregation‐induced emission properties. The typical shift in emission maxima to higher values was attributed to J‐aggregate formation in the aggregate state. Careful investigation of the crystal structures demonstrated abundant and intense intermolecular interactions, such as C−H...π and C−H...N hydrogen bonds, contributing to the remarkable mechanochromic luminescence performance of these compounds. The MCL properties of all the compounds were investigated using powder X‐ray diffraction, and the remarkable mechanochromic properties were attributed to J‐aggregate phenomena in the solid state. These results provide valuable insights into the structure‐property relationship of organic MCL materials, guiding the design of efficient organic MCL materials. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 18614728
- Volume :
- 19
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chemistry - An Asian Journal
- Publication Type :
- Academic Journal
- Accession number :
- 174845644
- Full Text :
- https://doi.org/10.1002/asia.202300910