Effects of Electron-Donor and Counter-Cation in Photoinduced Deboronative and Decarboxylative Aryl Radical Generation Using Two-Molecule Photoredox Catalysts.

This document discusses a study on the effects of electron-donor (ED) and counter-cation in the photoinduced generation of aryl radicals using two-molecule photoredox catalysts. The researchers focused on the use of arylboronic acids, arylboronic acid esters, and benzoic acids as substrates for generating aryl radicals. They found that the choice of ED and counter-cation had a significant impact on the yield of the desired products. The research provides valuable insights into factors affecting aryl radical generation and could contribute to the development of more efficient synthetic methods. [Extracted from the article]