Back to Search
Start Over
Pd(II)‐Catalyzed C−H Silylation of o‐Alkynylanilines Initiated by an Aminopalladation To Access Disilylated 2‐Phenyl‐1H‐indoles.
- Source :
-
Advanced Synthesis & Catalysis . 1/30/2024, Vol. 366 Issue 2, p183-187. 5p. - Publication Year :
- 2024
-
Abstract
- Herein a Pd(II)‐catalyzed C−H silylation of o‐alkynylanilines with hexamethyldisilane for the synthesis of disilylated 2‐phenyl‐1H‐indoles is reported. In this reaction, o‐alkynylanilines undergo an aminopalladation, C−H activation, and dealkylation sequence to form five‐membered C,C‐palladacycles, which then couple with hexamethyldisilane to construct one C−N bond and two C−Si bonds. This method provides an alternative strategy for C−H silylation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SILYLATION
*DEALKYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 366
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 175139865
- Full Text :
- https://doi.org/10.1002/adsc.202301119