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Atom-Precise Ligated Copper and Copper-Rich Nanoclusters with Mixed-Valent Cu(I)/Cu(0) Character: Structure–Electron Count Relationships.
- Source :
-
Molecules . Feb2024, Vol. 29 Issue 3, p605. 19p. - Publication Year :
- 2024
-
Abstract
- Copper homometallic and copper-rich heterometallic nanoclusters with some Cu(0) character are reviewed. Their structure and stability are discussed in terms of their number of "free" electrons. In many aspects, this structural chemistry differs from that of their silver or copper homologs. Whereas the two-electron species are by far the most numerous, only one eight-electron species is known, but more electron-rich nanoclusters have also been reported. Owing to the relatively recent development of this chemistry, it is likely that more electron-rich species will be reported in the future. [ABSTRACT FROM AUTHOR]
- Subjects :
- *COPPER
*ATOMIC clusters
*ELECTRONS
Subjects
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 29
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- 175371331
- Full Text :
- https://doi.org/10.3390/molecules29030605