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Highly dispersed thermally reduced graphene oxide in polypropylene assisted with in-situ Friedel-Crafts reaction and its thermo-oxidative stabilization effect.
- Source :
-
Carbon . Feb2024, Vol. 220, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Achieving uniform dispersion of nanofillers in a polymer matrix, particularly for incompatible compounds, remains a formidable challenge. In this study, thermally reduced graphene oxide (TrGO) sheets were effectively dispersed within a nonpolar polypropylene (PP) matrix using a two-step approach, leveraging the Friedel–Crafts reaction catalyzed by AlCl 3. The results showed that the size and number of TrGO aggregates were significantly reduced after AlCl 3 treatment. The thermo-oxidative stability in terms of oxidation induction time (OIT) of the PP/TrGO(Al) composite further improved by 2 times when 0.1 wt% TrGO was added to the PP matrix compared with that of the samples without AlCl 3 treatment. The improved thermo-oxidative stability and mechanical properties of PP/TrGO(Al) can be attributed to its superior radical scavenging efficiency, oxygen barrier effect, and effective load transfer afforded by the excellent dispersion of TrGO. This research highlights a pioneering methodology for enhancing both the dispersion of TrGO in a nonpolar polymer matrix and the thermo-oxidative resilience of the resultant composites. [Display omitted] • TrGO sheets were well-dispersed in PP matrix by using a two-step method through Friedel-Crafts reaction. • The thermo-oxidative stability of PP/TrGO(Al) composite were further improved due to the improvement of TrGO dispersion. • This can be attributed to the radical scavenging ability and oxygen-barrier effect of well-dispersed TrGO. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00086223
- Volume :
- 220
- Database :
- Academic Search Index
- Journal :
- Carbon
- Publication Type :
- Academic Journal
- Accession number :
- 175393728
- Full Text :
- https://doi.org/10.1016/j.carbon.2024.118895