Impact of chelating agents on precursor formation and efficiency of Ni/MgO-Al2O3 catalysts in dry reforming of methane.

Using cheap and non-toxic chelating agents during catalyst preparation is considered as an effective tool to control the particle size and to strengthen the metal-support interactions (MSI), while keeping the simplicity of the selected preparation method. The previous properties are useful to improve the catalyst activity, stability, and selectivity in dry reforming of methane (DRM). Therefore, we prepared a series of low Ni loading (2.5 wt%) catalysts supported over MgO-Al 2 O 3 (Mg/Al = 1.3) mixed oxide using the classic wet impregnation method modified with chelating agents (citric acid (CA), tartaric acid (TA) and diethylenetriaminepentaacetic acid (DTPA)) and subsequently evaluated these in DRM. Intensive catalyst characterization (ICP, BET, XRD, XPS, STEM, H 2 -TPR and O 2 -TPO) suggested the presence of different structure-activity relationships. Particularly, using chelating agents during catalyst preparation controlled the final particle size range, which in turn played a pivotal role in shaping the strength of the metal support interactions (MSI). These impacts were crucial to improve the activity, stability and to control the formation of coke deposits. Moreover, special focus was put on the catalytic testing of the outperforming sample (Ni(TA)/Mg 1.3 AlO x) prepared using tartaric acid as chelating agent under severe regimes prone to catalyst deactivation to demonstrate the benefits of the proposed preparation technique. [Display omitted] • Organic ligands affect Ni particle size and its metal-support interaction (MSI). • Adding tartaric acid (TA) during preparation gave the best catalyst. • Up to 60% less coking at high GHSV and excess CH 4. • Ni(TA)/Mg 1.3 AlO x lost only 10% conversion at 600 °C over 50 h runtime. • Ni reoxidation and coke deposition are the main reasons of catalyst deactivation. [ABSTRACT FROM AUTHOR]