Thermochemical energy storage in SrCO3 composites with SrTiO3 or SrZrO3.

Thermochemical energy storage offers a cost-effective and efficient approach for storing thermal energy at high temperature (∼1100 °C) for concentrated solar power and large-scale long duration energy storage. SrCO 3 is a potential candidate as a thermal energy storage material due to its high energy density of 205 kJ/mol of CO 2 during reversible CO 2 release and absorption. However, it loses cyclic capacity rapidly due to sintering. This study determined that the cyclic capacity of SrCO 3 was enhanced by the addition of either reactive SrTiO 3 or inert SrZrO 3 , where the molar ratios of SrCO 3 to SrZrO 3 were varied from 1:0.125 to 1:1. Thermogravimetric analysis over 15 CO 2 sorption cycles demonstrated that both materials retained ∼80 % of their maximum cyclic capacity on the milligram scale. Repeated measurements using gram scale samples revealed a decrease in maximum capacity to 11 % using a sample of SrCO 3 – 0.5 SrZrO 3 over 53 cycles, while the use of SrTiO 3 additives allowed for the retention of 80 % maximum capacity over 55 cycles. These findings highlight the potential of reactive additives in enhancing the performance of thermochemical energy storage systems, while providing valuable insights for the development of cost-effective materials. [Display omitted] • SrCO 3 is a cost-effective thermochemical energy storage material. • TGA shows both SrZrO 3 and SrTiO 3 additives increase cyclic capacity up to ∼80 %. • SrTiO 3 reduces sintering whereas SrZrO 3 does not prevent sintering. [ABSTRACT FROM AUTHOR]