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Mass synthesis of Pt/C catalysts with high Pt loading for low-overpotential hydrogen evolution.
- Source :
-
International Journal of Hydrogen Energy . Mar2024, Vol. 58, p268-278. 11p. - Publication Year :
- 2024
-
Abstract
- We present a facile and scalable method to synthesize Pt/C catalysts with high Pt loading (10–30 wt.%) using sodium polyacrylate resin (PAANa) as a multifunctional agent. PAANa can absorb H 2 PtCl 6 solution and form a gel, which can be converted into Pt/C catalysts by pyrolysis. PAANa acts as a water absorber, a Pt stabilizer, and a carbon precursor. The optimized catalyst, pyrolyzed at 800 °C with a 20 wt.% Pt loading, demonstrates Pt nanoparticles measuring 3.5 nm in size. It exhibits excellent stability and achieves a low overpotential of 43 mV at a current density of 10 mA cm−2 for the hydrogen evolution in alkaline media. The enhanced catalytic activity is due to the combined influence of the nanoscale Pt particles, the higher degree of graphitization, and the porous carbon substrate with a large surface area. We also demonstrate the scalability of the method by producing 100 g of the catalyst in the laboratory. [Display omitted] • Using PAANa as a multifunctional agent solves challenge of synthesizing high Pt loading Pt/C. • Pt/C catalyst demonstrates excellent performance with low overpotential and high stability. • Scalable method enables synthesis of Pt/C (100 g) for potential industrial applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 58
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 175642217
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2024.01.183