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Hydroxylation of Aryl Sulfonium Salts for Phenol Synthesis under Mild Reaction Conditions.
- Source :
-
Molecules . Feb2024, Vol. 29 Issue 4, p831. 14p. - Publication Year :
- 2024
-
Abstract
- Hydroxylation of aryl sulfonium salts could be realized by utilizing acetohydroxamic acid and oxime as hydroxylative agents in the presence of cesium carbonate as a base, leading to a variety of structurally diverse hydroxylated arenes in 47–95% yields. In addition, the reaction exhibited broad functionality tolerance, and a range of important functional groups (e.g., cyano, nitro, sulfonyl, formyl, keto, and ester) could be well amenable to the mild reaction conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HYDROXYLATION
*PHENOL
*SALTS
*PHENOLS
*FUNCTIONAL groups
*AROMATIC compounds
Subjects
Details
- Language :
- English
- ISSN :
- 14203049
- Volume :
- 29
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Molecules
- Publication Type :
- Academic Journal
- Accession number :
- 175648696
- Full Text :
- https://doi.org/10.3390/molecules29040831