Cu2O/WO3 S-scheme heterojunctions for photocatalytic degradation of levofloxacin based on coordination activation.

Heterogeneous photocatalytic degradation of antibiotic involves the activation of antibiotic molecules and the photocatalytic oxidation process. However, the simultaneous improvement of these processes is still a challenge. Herein, S-scheme heterojunctions consisted of Cu 2 O nanocluster with defective WO 3 nanosheets were constructed for efficient photocatalytic degradation of levofloxacin (LVX). The typical CNS-5 composite (5 wt% Cu 2 O/WO 3) achieves an optimal LVX degradation efficiency of 97.9% within 80 min. The spatial charge separation and enhancement of redox capacity were realized by the formation of S-scheme heterojunction between Cu 2 O and WO 3. Moreover, their interfacial interaction would lead to the loss of lattice oxygen and the generation of W5+ sites. It is witnessed that the C–N of piperazine ring and C O of carboxylic acid in LVX are coordinated with W5+ sites to build the electronic bridge to activate LVX, greatly promoting the further degradation. This work highlights the important role of selective coordination activation cooperated with S-type heterojunctions for the photocatalytic degradation and offers a new view to understand the degradation of antibiotics at molecular level. Efficient photocatalytic degradation of LVX over CNS-5 via coordination activation [Display omitted] • Modulation of electron structure and construction of unsaturated W active sites on Cu 2 O/WO 3 S-scheme heterojunctions. • Improvement of O 2 adsorption and reduction facilitating by oxygen deficiency. • The coordination and activation of levofloxacin with active sites boosted the photodegradation performance. • The photodegradation mechanism of the synergistic effect of S-scheme heterojunction and coordination activation. [ABSTRACT FROM AUTHOR]