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Embedding WS2 sheets parallel to SnS sheets for high performance in K-ion batteries.

Authors :
Wei, Shiying
Huang, Jianfeng
Wang, Yiting
Huang, Qingqing
Bai, Shuzhuo
Kajiyoshi, Koji
Liu, Yijun
Li, Zhenjiang
Cao, Liyun
Li, Jiayin
Source :
Chemical Engineering Journal. Mar2024, Vol. 484, pN.PAG-N.PAG. 1p.
Publication Year :
2024

Abstract

• This work designed a structure embedding WS 2 sheets parallel to SnS sheets. • SnS/WS 2 @C was obtained by the one-pot/multi-step solvothermal method. • Parallelly oriented WS 2 sheets provide K+ channels and stabilize the structure. • SnS/WS 2 @C exhibits superior electrochemical performance. Tin sulfide (SnS) exhibits the potential to be used as a superior-performance electrode material for potassium ion batteries. However, serious volume expansion and poor ion transport capacity hinder the applications of SnS. In order to solve the above problems, this work designed a structure that parallel WS 2 sheets were embedded in SnS sheets (SnS/WS 2 @C). SnS/WS 2 @C displayed excellent kinetic properties and stability when applied to anode materials for potassium ion batteries, as well as a high reversible capacity. SnS/WS 2 @C maintains a superior specific capacity of 619 mAh g−1 after 100 cycles at 0.2 A g−1 and 210 mAh g−1 at 10 A g−1. Such excellent performance is attributed to the fact that parallelly oriented WS 2 sheets provide fast channels for the transportation of potassium ions, which significantly improves the kinetic performance of the electrode, and can play an anchoring role for products in the process of charging and discharging by virtue of its excellent stability to effectively prevent structural fragmentation. This work provides new ideas for improving ion diffusion and enhancing the structural stability of transition metal layered compounds while maintaining the capacity advantage. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13858947
Volume :
484
Database :
Academic Search Index
Journal :
Chemical Engineering Journal
Publication Type :
Academic Journal
Accession number :
175849275
Full Text :
https://doi.org/10.1016/j.cej.2024.149455