Back to Search
Start Over
Temperature induced single-crystal to single-crystal transformation of uranium azide complexes.
- Source :
-
Chemical Communications . 3/14/2024, Vol. 60 Issue 21, p2966-2969. 4p. - Publication Year :
- 2024
-
Abstract
- The monomeric and dimeric uranium azide complexes {[(CH3)2NCH2CH2NPiPr2]2U(N3)2} (2) and {[(CH3)2NCH2CH2NPiPr2]2U(N3)2}2 (3) were synthesized by treating complex 1 with NaN3 at 60 and −20 °C, respectively. A temperature-induced single-crystal to single-crystal transformation of 3 to 2 was observed. The reduction of either 2 or 3 with KC8 yields a uranium nitride complex {[(CH3)2NCH2CH2NPiPr2]4U2(μ-N)2} (4). [ABSTRACT FROM AUTHOR]
- Subjects :
- *NITRIDES
*TEMPERATURE
*URANIUM
*URANIUM compounds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 175915631
- Full Text :
- https://doi.org/10.1039/d4cc00546e