Transition metal selenides as catalysts for electrochemical water splitting.

Hydrogen is a kind of clean renewable energy with great development potential. However, traditional electrocatalytic water splitting methods often require high energy consumption and expensive catalysts, which limits their practical application. Transition metal selenides (TMSes), as a new type of hydrogen production materials from electrolytic water, have been the focus of research in recent years. The basic principle of electrochemical water cracking and the preparation of TMSes are reviewed in this paper. The electrocatalysts for hydrogen evolution, oxygen evolution and integral water cracking based on TMSes, including single metal selenides, binary metal selenides, and multinary mixed metal selenides, are discussed. Finally, the future research direction and the development prospect of TMSes electrocatalysts are prospected. • Eley-Rideal and Langmuir-Hinshelwood mechanisms were used to analyze the OER reaction mechanism. • The production and properties of transition metal selenides in recent years are introduced in detail. • In this paper, transition metal selenides are introduced from single TMSes, binary TMSes and multinary mixed TMSes. • The physical properties and electronic structures of transition metal selenides are described in detail. [ABSTRACT FROM AUTHOR]