LCA of chemical grade silicon-organosilicon monomer synthesis by large capacity submerged arc furnace in China.

At present, the energy and environmental crisis is increasingly prominent, and how to solve the global energy and environmental problems is one of the challenges facing the world today. China is a major producer and consumer of organosilicon, so it is necessary to explore the stage of high energy consumption and high pollution in the organosilicon industrial chain. In 2022, the proportion of submerged arc furnaces of 25000 kVA and higher in China reached 40%. Further expansion of these furnaces in the future is inevitable. However, research on the life cycle assessment of organosilicon manufactured using large-capacity submerged arc furnaces is still blank.Therefore,in this paper, the life cycle assessment method is used to evaluate the synthesis process of chemical grade silicon-organosilicon monomer prepared by large capacity (33000 kVA) submerged arc furnace, and the dominant process in various environmental impacts is defined.At the same time, the measures to improve the production process of organosilicon monomer were put forward. In the production process of 1000 kg organosilicon monomer, global warming potential (GWP) contributed the most (73.43%) to the comprehensive environmental impact, followed by chronic public health impact (HTI, 10.55%). Energy consumption (EN) accounted for 8.50%, while resource consumption (RU) accounted for 7.43%. The contributions of other environmental factors were relatively small (0.09%).The energy consumption and environmental pollution in the production of organosilicon monomer can be reduced by strictly controlling the quality of raw materials into the furnace, using heat pump technology in the distillation unit, and comprehensively utilizing the heat of reaction by-products and steam condensate. [Display omitted] • This study is the first one in China to conduct LCA for the preparation of chemical grade silicon-organosilicon monomer synthesis process in 33000 kVA submerged arc furnace. It provides the best improvement suggestions for reducing the environmental load of the product life cycle process and achieving cleaner production. • In response to the national development policy of large-scale submerged arc furnace, the dominant process of preparing organosilicon monomer based on 33000 kva submerged arc furnace in various environmental impacts was clarified. • The main technical improvement directions are: Strictly control the quality of raw materials for submerged arc furnace; Strictly control the sulfur content and nitrogen content of carbonaceous reductant, and adopt the most suitable flue gas treatment technology route; Smelt with large submerged arc furnace; Use heat pump technology for distillation unit; Optimize the monomer synthesis device. [ABSTRACT FROM AUTHOR]