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Preparation of ultra-thin copper–aluminum composite foils for high-energy–density lithium-ion batteries through synergistic electroless plating and electroplating.
- Source :
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Applied Surface Science . Jun2024, Vol. 657, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
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Abstract
- [Display omitted] • Chemical plating and electroplating can be used to prepare ultra-thin copper–aluminum composite foils. • The process is shorter than the traditional aluminum-based copper plating process. • Preparation of transition layers by electroplating tin can form beneficial rivet structures. • The copper–aluminum composite foils have excellent bonding performance and electrical conductive properties. Copper-aluminum composite foils have the advantages of excellent electrical and mechanical properties, lightweight, and low cost. However, overcoming the equipment limitations of physical preparation methods to produce ultra-thin copper–aluminum composite foils with outstanding properties has been a challenge. Herein, smooth-faced, dense, and tightly bonded copper–aluminum composite foils are prepared using a combination of electroless plating and electroplating. This process involves the use of tin and nickel as transition layers, followed by electroplating the copper-clad layer. Ultra-thin copper–aluminum composite foils with a copper layer thickness ranging from 0.5 to 7 μm and a minimum square resistance of 4.6 mΩ can be prepared with a mass of 36.7 %-70 % of that of pure copper foils of the same thickness. These foils are expected to be used in a variety of energy storage components that require extreme lightweight. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 657
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 176034140
- Full Text :
- https://doi.org/10.1016/j.apsusc.2024.159804