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Synthesis and Properties of Azadibenzo[a,e]pyrenes.
- Source :
-
European Journal of Organic Chemistry . 3/25/2024, Vol. 27 Issue 12, p1-10. 10p. - Publication Year :
- 2024
-
Abstract
- Four different isomeric azadibenzo[a,e]pyrenes (benzo[4,10]anthra[9,1‐gh]isoquinolines and benzo[4,10]anthra[1,9‐fg]isoquinolines) were prepared by combination of Pd‐catalyzed Sonogashira and Suzuki cross‐coupling, Brønsted acid mediated cycloisomerization and Pd‐catalysed CH‐activation reactions. The optical properties have been studied by steady‐state absorption and emission spectroscopy in different solvents and during acid titration. Trifluoroacetic acid protonation strongly affects absorption and emission properties, with variations depending on the position of the nitrogen atom of the specific compound. Electrochemical analysis showed distinct oxidation and reduction potentials. DFT calculations provided further insights into electronic properties. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 27
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 176294990
- Full Text :
- https://doi.org/10.1002/ejoc.202301299