Efficient injection of gas tracers into rivers: A tool to study Surface water–Groundwater interactions.

Surface water (SW) - groundwater (GW) interactions exhibit complex spatial and temporal patterns often studied using tracers. However, most natural and artificial tracers have limitations in studying SW–GW interactions, particularly if no significant contrasts in concentrations between SW and GW exist or can be maintained for long durations. In such context, (noble) gases have emerged as promising alternatives to add to the available tracer methods, especially with the recent development of portable mass spectrometers, which enable continuous monitoring of dissolved gas concentrations directly in the field. However, long-duration gas injection into river water presents logistical challenges. To overcome this limitation, we present an efficient and robust diffusion-injection apparatus for labeling large amounts of river water. Our setup allows fine, real-time control of the gas injection rate, and is suitable for extended injection durations and different gas species. To illustrate the effectiveness of our approach, we present a case study where helium (He) is used as an artificial tracer to study river water infiltration into an alluvial aquifer. Our injection of He as a tracer increased the dissolved He concentration of the river water by one order of magnitude compared to air-saturated water concentration for 35 days. This experiment yields valuable information on travel times from the river to a pumping well and on the mixing ratios between freshly infiltrated river water and regional groundwater. • Gas can be injected into rivers by diffusion through a semi-permeable membrane. • Diffusive gas injection is much more efficient than bubbling injection. • Portable mass spectrometers allow on-site continuous monitoring of the injected gases. • Infiltrating river water tagged with gas tracers was identified in groundwater. • Gas tracers provide valuable insight into aquifer heterogeneity. [ABSTRACT FROM AUTHOR]