High-electrophilic (SiO)2Nb(OH)(=O) sites confined in silanol defects over Nb-Beta zeolite for efficient cyclic alkene epoxidation reactions.

[Display omitted] • Niobium species in 30Nb-Beta zeolite were anchored into silanol defects in form of (SiO) 2 Nb(OH)(=O). • High-electrophilic 30Nb-Beta could achieve a cyclohexene conversion of 51.1 % and TOF of 188.2 h−1. • H 2 O 2 activation pathway over (SiO) 2 Nb(OH)(=O) sites contains three steps. Dealuminated Beta zeolite has a large amount of silanol defects on its interface, which provides an ideal place for embedding metal species and creating metal active sites in a confined microenvironment. The confined metal sites as well as their surroundings are closely related to the reactant activation and transient state achievement. Hence, unraveling the confined metal sites is of great significance for the catalytic reaction process. Herein, niobium species were incorporated into the silanol defects over dealuminated Beta zeolite with a facile dry impregnation method, co-grinding the niobium precursor with dealuminated Beta zeolite support. The successful incorporation of niobium into the silanol defects for 30Nb-Beta zeolite was verified by DRIFT, 1H MAS NMR, UV–Vis and UV-Raman characterizations. XAS characterization and DFT calculations further disclosed that the confined Nb species existed as (SiO) 2 Nb(OH)(=O), containing two Si−O−Nb bonds, one Nb=O bond as well as one Nb−OH bond. The synthesized 30Nb-Beta zeolite catalyst displayed a superior cyclohexene conversion of 51.1%, cyclohexene oxide selectivity of 83.1% as well as TOF value of 188.2 h−1 ascribed to the inherent electrophilicity of Nb(V) for confined (SiO) 2 Nb(OH)(=O) species as well as the low oxygen transfer energy barrier for NbV−OOH species. Furthermore, the prepared 30Nb-Beta zeolite can be effectively employed to other cyclic alkene epoxidation reactions. [ABSTRACT FROM AUTHOR]