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Interlocking viologen-based lanthanide complexes for multifunctionality: Photochromism, electrochromism, photoluminescence, photomagnetism, and inkless printing and UV shielding applications.
- Source :
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Dyes & Pigments . Jun2024, Vol. 225, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
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Abstract
- The construction of molecular crystal materials with physical properties that can be dynamically controllable through various stimuli such as light and electricity is of extraordinary significance, while this remains a tremendous challenge. In this context, we demonstrate two novel 2-D multi-function viologen complexes, {[Ln(bcbp)(BDC)(CH 3 OH)(H 2 O) 2 ]·Cl·CH 3 OH·H 2 O} n (1-Eu , and 2-Dy ; H 2 bcbp·2Cl = 1,1′-bis(4-carboxyphenyl)-(4,4′-bipyridinium) dichloride; BDC = p -phthalic acid, and Ln = Eu, Dy). Due to the strong π-π interaction between viologen and BDC in the interlocked structure, both compounds exhibit rapid and reversible responses under the stimuli of UV light and electricity. Furthermore, accompanying the photochromic process, photo-modulated luminescent and photomagnetic behavior have been observed. Considering the excellent photochromic performance, the function filter paper and smart organic glass were successfully prepared and used for ink-free printing and UV light filtering. [Display omitted] • Two interlocking viologen-based lanthanide frameworks with strong π-π interactions were designed and synthesized. • The obtained compounds exhibited fast and reversible chromic under the stimuli of UV light and electricity. • Accompanied by the photochromic process, controllable photoluminescent and photomagnetic behavior have been observed. • The function filter paper and smart organic glass were successfully fabricated and their applications were explored. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01437208
- Volume :
- 225
- Database :
- Academic Search Index
- Journal :
- Dyes & Pigments
- Publication Type :
- Academic Journal
- Accession number :
- 176391343
- Full Text :
- https://doi.org/10.1016/j.dyepig.2024.112100