Carbon-neutral cement: The role of green hydrogen.

Business-as-usual (BAU) cement production is associated with a linear model that contributes significantly to global warming and is dependent on volatile energy markets. A novel circular model is proposed, by adding three power-to-gas system components to current production systems: a calcium-looping (CaL) CO 2 capture unit; water electrolysis for hydrogen and oxygen generation; and a methanation unit for synthetic natural gas (SNG) production. The paper presents the first analysis of the combined industrial-scale operation of these components in a closed loop, where the SNG fuels the cement kiln and the CaL unit, while the O 2 produced feeds it. The circular, hybrid, and BAU models are compared in three feasibility scenarios. It is concluded that the circular model outperforms the other alternatives environmentally, opening a potential pathway for the cement industry to achieve near net-zero CO 2 emissions, reduce energy dependence and improve economic efficiency. [Display omitted] • Innovative circular model proposed for carbon-neutral cement production. • Novel integration of CaL CO 2 capture, water electrolysis and methanation units. • Comparative techno-economic and environmental analysis conducted. • Circular model outperformed current and hybrid models. • Near net-zero CO 2 emissions and increased energy independence achieved. [ABSTRACT FROM AUTHOR]