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The role of lithium in hydrogen trapping and embrittlement of Al-Cu-Li alloys: Experimental study and DFT calculations.
- Source :
-
Journal of Alloys & Compounds . Jun2024, Vol. 988, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- The role of lithium in hydrogen embrittlement (HE) and trapping of Al-Cu-Li alloys were investigated in experimental and density functional theory (DFT) calculations. The tensile curves and fracture morphology show that the Li-contained samples are more sensitive to HE than the Li-free samples and the HE sensitivity increases with the aging time expansion. The Transmission Electron Microscope (TEM) analyses reveal that the number density of T 1 (Al 2 CuLi) precipitates increases about 66.8% with aging process, suggesting that HE sensitivity is exacerbated by T 1 precipitates. In addition, the lithium in T 1 precipitates, solid solution matrix and solute segregation grain boundaries (GBs) always has a high affinity to hydrogen according to DFT calculations, where T 1 precipitates have the highest hydrogen trapping energy with 0.736 eV/H atom. Moreover, the influence of hydrogen on Al-Cu-Li alloys was investigated using X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and electrochemical corrosion analysis. These analyses indicate that hydrogen exists in the form of hydrogen atoms, which results in a reduction in corrosion potential (E corr) from −676.3 mV to −699.3 mV by approximately 20 mV and an increase in corrosion current density (i corr) from 2.1×10−6 A/cm2 to 10.8×10−6 A/cm2 by an order of magnitude. The accumulated hydrogen atoms eventually lead to corrosion pits and blisters on the surface of alloys. [Display omitted] • The Li-contained alloys are more sensitive than the Li-free alloys to hydrogen embrittlement (HE). • The hydrogen trapping energy of T 1 precipitates is higher than those of other in DFT calculations. • The trapped hydrogen atoms decrease the surface corrosion resistance and lead to the corrosion pits and cracks. • The interactions between hydrogen and lithium intensify the transformation of the ductile to brittle fracture. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 988
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 176438212
- Full Text :
- https://doi.org/10.1016/j.jallcom.2024.174289