The Role of Diffusive Mixing in Current and Future Aviation Fuels at Relevant Operating Conditions.

With aviation's dependence on the high volumetric energy density offered by liquid fuels, Sustainable Aviation Fuels (SAFs) could offer the fastest path toward the decarbonization of aircrafts. However, the chemical properties of SAFs present new challenges, and research is needed to better understand their injection, combustion, and emission processes. While efforts such as the United States National Jet Fuel Combustion Program (NJFCP) that investigated several aspects in detail, certain processes were unfortunately beyond the reach of this program. One of them in particular is about droplet evaporation at relevant pressures and temperatures, and this represents the focus of the present paper. To address this gap, we characterized the evaporation and mixing of spray droplets injected into well-controlled thermodynamic environments at conditions relevant to modern and next-generation aero-engine combustors. We tested three fuels from the NJFCP, namely, an average Jet A fuel (A-2), an alcohol-to-jet fuel containing highly branched dodecane and hexadecane type components (C-1), and a blend made of 40% C-1 and 60% isoparaffins ranging from 9 to 12 carbon atoms (C-4). We also tested a single component normal alkane: n-dodecane, as well as an advanced bioderived cyclo-alkane fuel: bicyclohexyl. The time evolution of fuel droplets was monitored using high-speed long-distance microscopy in a specific configuration that enabled sharp images to be acquired at these extreme conditions. The collected images were processed using a purposely developed and trained machine learning (ML) algorithm to detect and characterize the droplets' evaporation regime. The results revealed different evaporation regimes, such as classical and diffusive. In agreement with previous studies, evaporation regimes appear to be controlled by ambient pressure, temperature, and fuel type. The measurements demonstrate that diffusive evaporation is relevant at high-pressure conditions, such as takeoff combustor pressures for modern commercial aircraft engines. However, classical evaporation mostly controls mixing at lower pressure, such as cruise altitude conditions. The ML analysis emphasized that multiple evaporation regimes co-existed at the same operating condition and no significant relationship was found between droplet size and evaporation regime. The findings of this work constitute a database for validating spray and droplet models that are necessary for implementing lower emissions fuels in aero-engines. [ABSTRACT FROM AUTHOR]