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One-step achieving high performance all-solid-state and all-in-one flexible electrochromic supercapacitor by polymer dispersed electrochromic device strategy.
- Source :
-
Journal of Colloid & Interface Science . Jul2024, Vol. 665, p969-976. 8p. - Publication Year :
- 2024
-
Abstract
- [Display omitted] Electrochromic devices (ECD) are widely used to regulate the transmittance of sunlight by applying a small voltage, but the drawbacks like complex layer-by-layer preparation procedures and inconvenient assembling process still exist. To address these problems, gel or solution-type all-in-one ECDs were recently developed for the simple structure, however, the leakage risk and absence of flexible large-area production have limited real applications. Herein, a novel all-solid-state and all-in-one flexible ECD was reported by originally developed polymer dispersed electrochromic device (PDECD) strategy. This all-solid-state flexible ECD could be efficiently prepared only by one step of phase separation without any extra treatment, and demonstrated outstanding stability (92.1 % of original ΔT remained after 10,000 cycles), high coloration efficiency (197 cm2/C), low power consumption (86.4 μW/cm2) and satisfied response time (≤12 s). Meanwhile, the stored power in ECD during coloring process could drive a LED with excellent cyclic stability (93 % of original capacity remained after 3000 cycles), implying that ECD could also serve as an idea electrochromic supercapacitor. What'more, a reported largest viologen-based all-solid-state flexible ECD (17.8 × 13.2 cm2) with robust bending resistance (up to 1000 bending cycles) was successfully fabricated with industrial roller coating technique, which indicated the huge potential in real world. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ELECTROCHROMIC devices
*SUPERCAPACITORS
*POLYMERS
*PHASE separation
*LEAKAGE
Subjects
Details
- Language :
- English
- ISSN :
- 00219797
- Volume :
- 665
- Database :
- Academic Search Index
- Journal :
- Journal of Colloid & Interface Science
- Publication Type :
- Academic Journal
- Accession number :
- 176546084
- Full Text :
- https://doi.org/10.1016/j.jcis.2024.03.131