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Reversible open–closed conformational switching of nano-size metalloporphyrin dimers triggered by light and temperature.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 4/21/2024, Vol. 53 Issue 15, p6758-6765. 8p. - Publication Year :
- 2024
-
Abstract
- The current work demonstrates the reversible control of substantial molecular motion in 'nano-sized' molecules, where two structural isomers can 'open' and 'close' their cavities in response to light or heat. The isomers differ widely in their photophysical properties, including colour, polarity, two-photon absorption and π-conjugation, and can easily be separated through column chromatography and thus have wide applicability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 53
- Issue :
- 15
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 176611111
- Full Text :
- https://doi.org/10.1039/d4dt00223g