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Three-dimension TiO2@NiFe-layered double hydroxide core-shell heterostructures for enhanced photocatalytic phenol hydroxylation.
- Source :
-
Optical Materials . Apr2024, Vol. 150, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- One-step selectively photocatalytic phenol hydroxylation to produce Dihydroxybenzenes (DHB) is an attractive and challenging strategy. However, the rapid recombination of photogenerated carriers existed in single component photocatalyst seriously hinders the photocatalytic efficiency. The heterojunction strategy can optimize the band structure of the photocatalyst, and effectively improve the carriers' separation and transfer during the photocatalytic process. Herein, we successfully designed and prepared a 3D TiO 2 @Ni 3 Fe 1 -LDH core-shell heterostructure photocatalyst by coupling TiO 2 nanorods with Ni 3 Fe 1 -LDH nanosheets for the photocatalytic phenol hydroxylation to produce DHB. The results showed that the 3D TiO 2 @Ni 3 Fe 1 -LDH core-shell heterostructure had a suitable energy band structure for the photocatalytic phenol hydroxylation and the heterostructure accelerated the carriers' separation and transfer. Meanwhile, the high porosity and abundant active sites were conducive to the adsorption of H 2 O 2 and the photogenerated carriers transfer efficiency from the photocatalyst to H 2 O 2. The 3D TiO 2 @Ni 3 Fe 1 -LDH core-shell heterostructure showed excellent photocatalytic performance of phenol hydroxylation, where the phenol conversion was 48.6%, and the selectivity of DHB was 81.1% at 25 °C and 4 h of light illumination. Furthermore, the as-prepared photocatalysts exhibited good stability after four cycles of experiment. This work provided a convenient and efficient method for the green synthesis of DHB. 3D TiO 2 @NiFe-LDH core-shell heterostructures photocatalysts were fabricated by coupling anatase TiO 2 nanorods with NiFe-LDH nanosheets. The 3D TiO 2 @NiFe-LDH core-shell heterostructures with a suitable energy band structure for the photocatalytic phenol hydroxylation and the heterostructure accelerates the carrier separation rate showed excellent photocatalytic performance of phenol hydroxylation. [Display omitted] • 3D TiO 2 @NiFe-LDH core-shell heterostructures were fabricated. • Core-shell heterostructures accelerated photogenerated carriers' separation and transfer. • Uniformly growth of LDHs improved conductivity and light absorption of the photocatalyst. • TiO 2 @Ni 3 Fe 1 -LDH performed well in selectively photocatalytic phenol hydroxylation. • The photocatalytic phenol hydroxylation followed the mechanism dominated by.•OH species. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHENOL
*HETEROSTRUCTURES
*HYDROXYLATION
*TITANIUM dioxide
*ENERGY bands
Subjects
Details
- Language :
- English
- ISSN :
- 09253467
- Volume :
- 150
- Database :
- Academic Search Index
- Journal :
- Optical Materials
- Publication Type :
- Academic Journal
- Accession number :
- 176631013
- Full Text :
- https://doi.org/10.1016/j.optmat.2024.115296