Constructing porous ZnFC-PA/PSF composite spheres for highly efficient Cs+ removal.

• The adsorption capacity of ZnFC-PA/PSF composite spheres for Cs+ was 305.38 mg/g. • Its practicability is superior than of most previously reported adsorbents. • A fixed bed reactor loaded with ZnFC-PA/PSF spheres was used for cesium removal. • The effects of operating parameters on the breakthrough curves were investigated. Radioisotope leaking from nuclear waste has become an intractable problem due to its gamma radiation and strong water solubility. In this work, a novel porous ZnFC-PA/PSF composite sphere was fabricated by immobilization of ferrocyanides modified zinc phytate into polysulfone (PSF) substrate for the treatment of Cs-contaminated water. The maximum adsorption capacity of ZnFC-PA/PSF was 305.38 mg/g, and the removal efficiency of Cs+ was reached 94.27% within 2 hr. The ZnFC-PA/PSF presented favorable stability with negligible dissolution loss of Zn2+ and Fe2+ (< 2%). The ZnFC-PA/PSF achieved high-selectivity towards Cs+ (K d = 2.24×104 mL/g) even in actual geothermal water. The adsorption mechanism was inferred to be the ion-exchange between Cs+ and K+. What's more, ZnFC-PA/PSF worked well in the fixed-bed adsorption (E = 91.92%), indicating the application potential for the hazardous Cs+ removal from wastewater. [Display omitted] [ABSTRACT FROM AUTHOR]