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CTAC-assisted monoclinic BiVO4 with oxygen defects for efficient photocatalytic performances: A combined experimental and DFT study.
- Source :
-
Journal of Alloys & Compounds . Jun2024, Vol. 990, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Developing a photocatalyst with high photocatalytic efficiency, chemical stability, and self-degradation capability is essential for optimizing photodegradation processes in environmental applications. In this study, we synthesized a monoclinic BiVO 4 photocatalyst whose surface morphology was modulated by hexadecyltrimethylammonium chloride (CTAC) using a facile hydrothermal method. Experimental results demonstrated a substantial increase in the degradation rate (99%) for the CTAC-modified monoclinic BV/CT25 photocatalyst (with an initial CTAC concentration of 25 g/L) compared to the CTAC-free tetragonal BiVO 4 photocatalyst (73%). This highlights the effective enhancement of photocatalytic degradation performance through CTAC modification. Furthermore, density functional theory (DFT) calculations revealed that the band gap of BV/CT25 remained unchanged, suggesting that changes in oxygen vacancies (OVs) and density of states, along with the porous lattice structure, contributed to the improved performance. These findings were further supported by FESEM, as well as EPR and XPS characterizations. In addition, photodegradation tests at various pH conditions and cyclic tests suggested that the modification enhanced the morphological stability and reusability of the modified BiVO 4 photocatalysts. Overall, this study provides valuable insights into the design of next-generation photocatalysts, leveraging surfactants to control surface properties and emphasizing the key attributes of high photocatalytic efficiency, chemical stability, and improved reusability. [Display omitted] • Hexadecyltrimethylammonium chloride regulates the morphology of monoclinic BiVO 4. • Oxygen defects increased the photocatalytic performance of BiVO 4 caused by CTAC. • CTAC-modified monoclinic BV/CT25 (CTAC 25 g/L) gave RhB efficiency >97%. • DFT calculations revealed oxygen vacancies and stability of BV/CT25. • The enhanced photocatalytic and stability performance acquired. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 990
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 176760027
- Full Text :
- https://doi.org/10.1016/j.jallcom.2024.174404