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A cyan-green-emitting garnet-structured Lu3-xScxAl2-yScyAl3-zSczO12: Ce3+ phosphor ceramics towards high-color-quality laser-driven lighting.
- Source :
-
Ceramics International . Jun2024, Vol. 50 Issue 12, p21074-21082. 9p. - Publication Year :
- 2024
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Abstract
- For the laser-driven lighting, traditional phosphor ceramics (PCs), such as Y 3 Al 5 O 12 : Ce3+ (YAG: Ce) PC and Lu 3 Al 5 O 12 : Ce3+ (LuAG: Ce) PC, usually show a wide "cyan cavity" due to the ultra-narrow emission bandwidth (∼2 nm) of the blue laser diode (LD). In this regard, the attainable color rendering (Ra) is always <90 even via the combination of "YAG: Ce/LuAG: Ce + CaAlSiN 3 :Eu2+". Evidently, the "cyan gap" is the bottleneck issue to attain high-color-quality laser-driven lighting. As such, we develop a novel cyan-green-emitting garnet-structured solid-solution Lu 3- x Sc x Al 2- y Sc y Al 3- z Sc z O 12 : Ce3+ (abbreviated as LuScAG: Ce) PCs, derived from the LuAG: Ce PC. A comparative study is conducted to unearth its microstructure, luminescence properties and promising availability. It can be found that the LuScAG: Ce PCs shows large full width at half maximum (FWHM) and abundant cyan emission. Upon material optimization, bright cyan-green emission can be generated with internal quantum efficiency (IQE) of 87.4 % and FWHM of 87.17 nm. Remarkably, this new material yields high-power emitting light with luminous flux (LF) of 3230 lm and luminous efficacy (LE) of 89.7 lm/W upon 36.0 W blue LD driven in rotatory excitation mode, which can serve as an efficient laser color converter. As expected, due to the achieved affluent cyan emissive components of developed LuScAG: Ce PCs, the lighting source based on "LuScAG: Ce PC + CASN: Eu phosphor-in-glass film (PiGF)" shows high color quality with Ra of 90.6 and R12 (related with the cyan cavity) of 85.0. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02728842
- Volume :
- 50
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Ceramics International
- Publication Type :
- Academic Journal
- Accession number :
- 176924852
- Full Text :
- https://doi.org/10.1016/j.ceramint.2024.03.216