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Synthesis of Uniformly Covered Fe-MOF@COF Heterostructures for Boosting Photo-Fenton Catalysis.
- Source :
-
Journal of Inorganic & Organometallic Polymers & Materials . Mar2024, Vol. 34 Issue 3, p1309-1324. 16p. - Publication Year :
- 2024
-
Abstract
- Fe-based MOFs (Fe-MOFs) are excellent photocatalysts and have synergy well with Fenton reagents relative to other MOFs. In this work, a series of uniformly covered NH2-Fe-MIL-88B@TpPa-1-COF composites were synthesized using an in-situ anchoring growth strategy, which used F127 as functional molecule to decorate NH2-Fe-MIL-88B nanoparticles to eliminate their surface electrostatic repulsion with Tp molecules during the subsequent coating procedure. Meanwhile, the -NH2 groups in the skeleton of NH2-Fe-MIL-88B could also be used as anchors to covalently connect TpPa-1-COF shell and migration channels for effective charge transfer. This uniformly covered core–shell structure would endow these composites with much more contact area and imine bond linkage between the Fe-MOFs core and COFs shell. Compared with the random packing structure, the uniformly covered Fe-MOF@COF-3 composite possessed a higher proportion of Fe2+ to Fe3+. As a result, the optimized Fe-MOF@COF-3 catalyst could achieve the highest photo-Fenton degradation efficiency of 93.9% for tetracycline hydrochloride (TC⋅HCl), which was much higher than 54.8% of pure NH2-Fe-MIL-88B. In addition, the uniform TpPa-1-COF shell could further effectively enhance the stability of NH2-Fe-MIL-88B by protecting Fe ions from leaching, and the toxicity of the water samples treated with our photo-Fenton degradation process declined obviously. All these merits will endow Fe-MOF@COF-3 photo-Fenton catalyst great potential application value as in the field of environmental governance. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CATALYSIS
*HETEROSTRUCTURES
*CHARGE transfer
*WATER sampling
*PHOTOCATALYSTS
Subjects
Details
- Language :
- English
- ISSN :
- 15741443
- Volume :
- 34
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Inorganic & Organometallic Polymers & Materials
- Publication Type :
- Academic Journal
- Accession number :
- 177000385
- Full Text :
- https://doi.org/10.1007/s10904-023-02893-5