Photoluminescence and transport properties of fluorinated graphene via a weak fluorination strategy.

The zero-bandgap properties of graphene (Gr) limit its various applications. Fluorination is an alternative strategy to open the bandgap to broaden its applications. However, traditional fluorination methods are detrimental to human health and contribute extensively to environmental pollution. Here, we develop a simple and safe process of weak fluorination that introduces fluorine atoms into Gr, breaking its zero-bandgap structure. This strategy is more environmentally friendly, risk-free, and harmless to humans, making it suitable for large-scale production. Through this highly controllable weak fluorination process, micro-area selective fluorination is achieved and induces excellent photoluminescence characteristics but maintains a high mobility, compared to the pristine Gr with zero bandgap. The degree of fluorination determines the photoelectric and transport properties of Gr. This work provides an experimental foundation for developing materials based on fluorinated graphene and designing high-performance functional devices. [ABSTRACT FROM AUTHOR]