Recent Advances in Palladium‐Catalyzed Asymmetric Heck/Tsuji–Trost Reactions of 1,n‐Dienes.

Transition–metal catalyzed tandem asymmetric reactions were powerful tools to access various chiral compounds. Many strategies have been developed for the coupling of 1,n‐dienes with aryl halides via a tandem Heck/Tsuji–Trost process. However, the control of regio‐ and stereo‐chemistry remains a challenging task. This minireview details the recent advances in the field of asymmetric Heck/Tsuji–Trost reactions catalyzed by palladium complex, which have opened new opportunities and expanded our understanding in this area of research in recent years. [ABSTRACT FROM AUTHOR]