Enhanced Mass Activity and Durability of Bimetallic Pt-Pd Nanoparticles on Sulfated-Zirconia-Doped Graphene Nanoplates for Oxygen Reduction Reaction in Proton Exchange Membrane Fuel Cell Applications.

Highlights: In this work, graphene nanoplates (GNPs) with a supreme medium were obtained. Pt particles (4.50 nm) were uniformly dispersed on the surface of S-ZrO2-GNP support. The Pt-Pd/S-ZrO2-GNPs exhibited higher ECSA than Pt-Pd/ZrO2-GNPs and Pt/C. Pt-Pd/S-ZrO2-GNPs exhibited higher ORR mass activity than other studied electrodes. Pt-Pd/S-ZrO2-GNPs exhibited low charge transfer resistance in EIS measurements. Developing highly active and durable Pt-based electrocatalysts is crucial for polymer electrolyte membrane fuel cells. This study focuses on the performance of oxygen reduction reaction (ORR) electrocatalysts composed of Pt-Pd alloy nanoparticles on graphene nanoplates (GNPs) anchored with sulfated zirconia nanoparticles. The results of field emission scanning electron microscopy and transmission electron microscopy showed that Pt-Pd and S-ZrO2 are well dispersed on the surface of the GNPs. X-ray diffraction revealed that the S-ZrO2 and Pt-Pd alloy coexist in the Pt-Pd/S-ZrO2-GNP nanocomposites without affecting the crystalline lattice of Pt and the graphitic structure of the GNPs. To evaluate the electrochemical activity and reaction kinetics for ORR, we performed cyclic voltammetry, rotating disc electrode, and EIS experiments in acidic solutions at room temperature. The findings showed that Pt-Pd/S-ZrO2-GNPs exhibited a better ORR performance than the Pt-Pd catalyst on the unsulfated ZrO2-GNP support and with Pt on S-ZrO2-GNPs and commercial Pt/C. [ABSTRACT FROM AUTHOR]