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Increase in the Two-Photon Absorption Cross Section of Styryl Dye in Supramolecular Complexes with Cucurbiturils.
- Source :
-
High Energy Chemistry . Jun2024, Vol. 58 Issue 3, p302-305. 4p. - Publication Year :
- 2024
-
Abstract
- Using fluorescence spectroscopy, the two-photon absorption cross sections of aqueous solutions of the styryl dye trans-4-[4-(dimethylamino)styryl]-1-methylpyridinium iodide (DASPI) and its inclusion complexes with cucurbit[n]urils (CB[n] n = 6–8) have been measured. A nonmonotonic dependence of the cross section on the excitation wavelength and on the cavitand cavity size has been revealed. Compared to the free dye, a sevenfold increase in the two-photon absorption cross section has been observed in DASPI inclusion complexes with CB[8] at an excitation wavelength of 980 nm. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00181439
- Volume :
- 58
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- High Energy Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 177190610
- Full Text :
- https://doi.org/10.1134/S0018143924700140