Back to Search
Start Over
Umgehung von Ammoniak: Von N2 zu stickstoffhaltigen Heterocyclen ohne N1‐Zwischenprodukte oder Übergangsmetalle.
- Source :
-
Angewandte Chemie . 5/21/2024, Vol. 136 Issue 21, p1-5. 5p. - Publication Year :
- 2024
-
Abstract
- The article describes the bypassing of ammonia in the synthesis of nitrogen-containing heterocycles. Diboradiazen compounds, derived from boron-mediated activation of dinitrogen (N2), were used. New heterocyclic compounds, which are BN-isosteres of thiophene and 1,3-oxazole, were formed through reactions with sulfur and acetic anhydride. Two new heterocyclic compounds, 1-Dur and 1-Mes, were synthesized and complete the synthesis routes. The structures of the compounds exhibit certain features of aromaticity. The study emphasizes the potential benefits of main group element-mediated N2 reductions. The project was funded by various organizations and there are no conflicts of interest. [Extracted from the article]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 136
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 177191714
- Full Text :
- https://doi.org/10.1002/ange.202402777