Precise synthesis of three-arm star polymethacrylates with high emission efficiency both in solution and in the solid state.

Dual-state (solution and solid) highly emissive three-arm star polymethacrylates were synthesized via ATRP using TPA-BKI-3Br as initiator. [Display omitted] • Three-arm star polymethacrylates with bright luminescence in both solution and solid state were prepared and studied efficiently. • The photophysical characteristics of the polymethacrylates were notably impacted by the space charge transfer between the TPA-BKI unit and polymer chains. Organic/polymeric fluorescent materials with bright emission both in solution and in the solid state have garnered growing interest in biological and optoelectronic fields. Herein, triphenylamine-derived boron ketoimine (TPA-BKI-3Br) was utilized as the initiator for atom transfer radical polymerization (ATRP) to prepare dual-state emission three-arm star polymethacrylates. Due to the intramolecular charge transfer (ICT) effect and highly distorted structure of the TPA-BKI unit, as well as the polymer arms constraining intramolecular motions, the resultant polymers displayed significant emission in solution. In the aggregated and solid states, the photophysical characteristics of the resultant polymethacrylates were notably impacted by the space charge transfer between the TPA-BKI unit and polymer chains. In addition, the TPA-BKI-based poly(2-(dimethylamino)ethyl methacrylate) (TPA-BKI-(PDMAEMA)3) exhibited fluorescence responses to temperature variations owing to the presence of dimethylamino group. This study presents an approach for the advancement of dual-state emission polymeric materials. [ABSTRACT FROM AUTHOR]