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Ni(2,2′:6′,2′′-terpyridine)2: a high-spin octahedral formal Ni(0) complex.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 5/28/2024, Vol. 53 Issue 20, p8550-8554. 5p. - Publication Year :
- 2024
-
Abstract
- We have synthesised and characterised the complex Ni(tpy)2 (tpy = 2,2′:6′,2′′-terpyridine). This formally Ni(0) complex is paramagnetic both in the solid state and in solution (S = 2). The crystal structure shows an octahedral geometry, with molecules arranged in independent dimers involving π-stacking between pairs of complexes. Magnetic measurementes and DFT calculations suggest the existence of temperature-dependent intermolecular antiferromagnetic coupling in the solid state. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SOLID solutions
*CRYSTAL structure
*DIMERS
*MOLECULES
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 53
- Issue :
- 20
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 177354220
- Full Text :
- https://doi.org/10.1039/d3dt04247b