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Dehalogenative deuteration of alkyl and aryl bromides by thiyl radical catalysis under visible-light irradiation.
- Source :
-
Chemical Communications . 5/25/2024, Vol. 60 Issue 42, p5526-5529. 4p. - Publication Year :
- 2024
-
Abstract
- Herein, we report a mild and practical method for the deuteration of alkyl and aryl bromides by a thiyl radical catalyst and halogen-atom transfer (XAT) using disulfides and silanes under visible-light irradiation. In this study, various organic bromides such as 1°, 2°, and 3°-alkyl bromides and aryl bromides were converted to deuterated products in good to excellent yields and D-incorporation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 177376946
- Full Text :
- https://doi.org/10.1039/d4cc00474d