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Palladium/norbornene-catalyzed diversified trifunctionalization of aryl-thianthreniums.
- Source :
-
Chemical Communications . 5/25/2024, Vol. 60 Issue 42, p5558-5561. 4p. - Publication Year :
- 2024
-
Abstract
- A novel Catellani-type conversion is reported using aryl-thianthreniums (aryl-TTs) instead of aryl halides. Three classes of ortho-dual C–H functionalization involving alkylation, amination, and deuterated methylation and five types of ipso-operation including alkenylation, cyanation, methylation, hydrogenation, and alkynylation all proceed well in this procedure. In this conversion, aryl-TTs exhibit satisfactory reactivity and feature the advantage that the leaving TT unit can be recovered. More strikingly, this finding represents a new chemistry conversion of aryl-TTs, wherein contiguous tri-functionalization in a single chemical manipulation is realized. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENYLATION
*ARYL halides
*METHYLATION
*HYDROGENATION
*AMINATION
*ALKYLATION
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 60
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 177376961
- Full Text :
- https://doi.org/10.1039/d4cc01426j