Enhancing selective nitrate-to-ammonia electrocatalysis with high-performing Ni2P embedded nitrogen phosphide doped carbon (NPC) deposited on CP: Unprecedented performance and stability.

One of the biggest challenges to the sustainable manufacture of liquid ammonia and the prevention of worldwide water contamination is the development of effective electrocatalysts for the electrochemical reduction of nitrate (NO 3 −) to NH 3 with high stability. Herein, a highly active and serviceable electrocatalyst is synthesized by pyrolysis, composed of nanostructure nickel phosphide (Ni 2 P) embedded in nitrogen phosphide doped carbon (NPC) followed by deposition on carbon paper (CP) to improve the electrocatalytic nitrate reduction. Various characterization techniques investigate the crystallinity, morphology, and chemical components of the Ni 2 P-NPC/CP nanoparticles. The results support the formation of nanostructure Ni 2 P and strong synergistic interactions between Ni 2 P and NPC, which resulted in substantial active sites and high electrical conductivity. Excellent performance of Ni 2 P-NPC/CP nanoparticles is achieved for electrocatalytic NO 3 − reduction with an NH 4 + yield rate of 2.468 mg h−1 mg cat. −1 and Faradaic efficiency (FE) of 84.6% at −1.2 V vs. RHE. Additionally, Ni 2 P-NPC/CP nanoparticles exhibit exceptional robustness and endurance. Studies using isotope labeling have been carried out, and the results show that nitrate reduction produces ammonia. Ni 2 P-based electrocatalysts can effectively treat nitrate wastewater to recover ammonia and facilitate its use in diverse industrial applications. • Ni 2 P-NPC/CP offers a highly active and durable electrocatalyst for the conversion of nitrate to ammonia. • Ni 2 P-NPC/CP achieved NH 4 + yield rate of 2.468 mmol h−1 mgcat−1 and Faradaic efficiency of 84.6% at −1.2 V. • The unique Ni 2 P-NPC/CP ensures robustness and practical options for continuous nitrate reduction processes. • Ni 2 P-NPC/CP offers a carbon-free energy solution through the selective conversion of nitrate to NH 3. [ABSTRACT FROM AUTHOR]