Confining Zero‐Valent Platinum Single Atoms in α‐MoC1−x for pH‐Universal Hydrogen Evolution Reaction.

Single‐atom electrocatalysts (SACs) toward hydrogen evolution reaction (HER) have been extensively studied owing to their high mass activity and atom utilization. Although platinum (Pt) based SACs have been reported frequently, optimizing the metal–support interaction to achieve low valence state Pt species is still a challenge. Here, the carbon supported α‐MoC1−x nanoparticles are used to anchor zero‐valent Pt single atoms (PtSA/α‐MoC1−x@C) as electrocatalyst for pH‐universal HER. The PtSA/α‐MoC1−x@C with optimized Pt loading of 0.75 wt% shows a low overpotential (21, 12, and 36 mV at 10 mA cm–2) and high turnover frequencies (27.00, 31.98, and 21.39 H2 s–1 at 100 mV) for HER under alkaline, acidic, and neutral electrolyte conditions. Experimental evidence combing density functional theory calculations confirm that the charge polarization leads to a zero‐valence state of Pt single atom and further optimized the adsorption/desorption energy of intermediates, further accelerating the reaction dynamics for HER. [ABSTRACT FROM AUTHOR]