Relationship between Lennard-Jones potential and physico-chemical parameters.

We developed in this paper the used methodology to describe the Lennard-Jones potential of two atoms in rare gas. In this treatment we supposed that one atom could be described by a harmonic oscillator. The interaction potential is developed at short and long ranges. The results showed that the obtained physico-chemical parameters such as the oscillator frequency, the atom mass, and the atom charge well reproduce the Lennard-Jones potential. Then the potential well depth and the effective equilibrium diameter are expressed in function of the oscillator frequency, the atom mass and charge. [ABSTRACT FROM AUTHOR]