Formkomplementäre Multikomponenten Assemblierung von Niedrigsymmetrischen Co(III)Salphen Koordinationskäfigen.

This article discusses the synthesis and characterization of heteroleptic coordination cages using cobalt as the metal center. The authors describe the rational combination of ligands to create three-dimensional cage structures and explore the self-sorting behavior of different ligands in the formation of these cages. They also perform calculations to understand the relative energies of different cage formations. The authors successfully synthesize a target compound and confirm its structure through various analytical techniques. The article provides detailed information on the synthesis and characterization of these cages, highlighting their potential applications in enzymatic catalysis and molecular machines. [Extracted from the article]