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Functionalized N-doped carbon nanosheets derived from metal−organic framework as oil-based lubricant additives for improved tribological performance.
- Source :
-
Tribology International . Sep2024, Vol. 197, pN.PAG-N.PAG. 1p. - Publication Year :
- 2024
-
Abstract
- Herein, the functionalized N-doped carbon nanosheet (N@PCNs) was successfully achieved through pyrolysis of metal−organic framework (MOF) and then surface modification with anti-wear agent. Firstly, the N@PCNs was obtained via carbonization of copper pyridine coordination polymer-based MOFs. Then tannic acid (TA) cross-linked by polyethylenimine (PEI) via Michael addition was grafted on the N@PCNs surfaces. Finally, the anti-wear agent 2,5-dimercaptothiadiazole dimer (DTD) was grafted onto N@PCNs via Michael addition reaction with TA to obtain DTD-N@PCNs. The average COF of 500SN decreases to 0.110 from 0.195, accompanied by 69.3% reduction in wear volume with 1.00 wt% DTD-N@PCNs addition. The lubrication performance is ascribed to the formation of a stable protective film through DTD-N@PCNs facilitating tribochemical reactions, preventing direct contact of the ball-disc pairs. [Display omitted] • The functionalized N@PCNs was prepared through pyrolysis of copper-based MOFs and then surface modification with DTD. • The resultant DTD-N@PCNs exhibits improved anti-wear and friction reducing properties when used as a lubricant additive. • The lubrication performance was attributed to the polishing effect and mending effect of DTD-NN@PCNs, along with formation of a protective film. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0301679X
- Volume :
- 197
- Database :
- Academic Search Index
- Journal :
- Tribology International
- Publication Type :
- Academic Journal
- Accession number :
- 177756029
- Full Text :
- https://doi.org/10.1016/j.triboint.2024.109795