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Photoinduzierte Ruthenium‐katalysierte C−H Arylierungspolymerisation bei Raumtemperatur.

Authors :
Michiyuki, Takuya
Maksso, Isaac
Ackermann, Lutz
Source :
Angewandte Chemie. 6/17/2024, Vol. 136 Issue 25, p1-6. 6p.
Publication Year :
2024

Abstract

This article discusses a new method for synthesizing π-conjugated polymers using a ruthenium-catalyzed C-H arylation polymerization. The method involves using visible light irradiation at room temperature, resulting in high yields and high molecular weights of the polymers. The article also explores the use of photochemistry and C-H activation in polymer synthesis, highlighting the advantages of using light energy for mild reactions with high chemoselectivity and functional group tolerance. The document presents a study on the ruthenium-catalyzed polymerization of phenyloxazolines, investigating reaction conditions, reactivity of different arylbromides, and the synthesis of terpolymers. The research demonstrates the potential of ruthenium-catalyzed polymerization for various applications in polymer chemistry. [Extracted from the article]

Details

Language :
English
ISSN :
00448249
Volume :
136
Issue :
25
Database :
Academic Search Index
Journal :
Angewandte Chemie
Publication Type :
Academic Journal
Accession number :
177773177
Full Text :
https://doi.org/10.1002/ange.202400845